All chapters
CC-CV profileCharger selectionLead-acid trapFast charging

More lithium packs are destroyed by their chargers than by their duty cycles. The two mistakes that do it — a lead-acid charger on a lithium pack, and charging below freezing — are both easy to make, both invisible on the day, and both entirely preventable with equipment that already exists.

13.1The CC-CV profile

Lithium charging has two phases and, for a deeply discharged cell, a third that comes first.

13.1.1Trickle / pre-charge

For cells below roughly 2.5 V, a low current of about 0.05C until the cell is safe to charge normally. Skipping this on a deeply discharged cell is how a recovery attempt becomes a thermal event.

13.1.2CC — constant current

The charger holds current constant and the cell voltage rises. This delivers roughly 80 to 90 per cent of the capacity and occupies most of the time.

13.1.3CV — constant voltage

Once the cell reaches its cut-off — 3.65 V for LFP, 4.2 V for NMC — the charger holds that voltage and current tapers away. Charging ends when current falls to a termination threshold, typically 0.02 to 0.05C.

Per-cell voltage protection windowsafe operating band2.20VUnder-voltage cut-off2.60VUnder-voltage release3.20VNominal 3.2V3.40VBalance turn-on3.65VCell charge limit3.75VOver-voltage cut-off22.252.52.7533.253.53.75Per-cell voltage (V)
Figure 1 — Typical per-cell thresholds, from the over-discharge cut-off at 2.20V through the safe operating band to the over-charge cut-off at 3.75V. Note that the cell datasheet caps charging at 3.65V, below the BMS trip point.

Important

The charger must stop, not float. Lead-acid chargers hold a float voltage indefinitely because lead-acid needs it. LFP does not, and holding a lithium pack at high state of charge accelerates SEI growth and calendar ageing — the mechanism in Chapter 3. A charger that floats is slowly destroying the pack it is connected to.

13.2Choosing a charger

  • Voltage must match the S count and the chemistry. A 20S LFP pack needs a 73.0 V charger — 20 × 3.65 V. Not 72 V, not 73.5 V.
  • Current rating sets charge time and thermal load. 0.2 to 0.5C is the range that trades acceptable time against long life. On a 100 Ah pack that is 20 to 50 A.
  • Communication changes what is possible. A smart charger talking to the BMS over CAN can be commanded to reduce current, stop, or refuse to start when the pack is below 0°C. A dumb charger cannot be told anything, so every protection has to live in the BMS and be enforced by disconnecting.
  • Termination behaviour is a specification. Ask what the charger does when current reaches the taper threshold. “It goes green” is not an answer; ask whether output actually ceases.

13.3The lead-acid charger trap

This is the single most common and most damaging field error in the Indian three-wheeler market, and it happens because the numbers look close enough to work.

A 60 V lead-acid charger against a 20S LFP pack

Lead-acid chargerWhat LFP needs
Peak voltage~73.5 V73.0 V
Equalisation stageDeliberately overcharges to stir electrolyte and desulphate platesNone. LFP has no equalisation phase and no tolerance for one.
Float stageHolds voltage indefinitely to offset self-dischargeNone. Float holds the pack at high SOC and accelerates calendar ageing.
TerminationDoes not terminate — transitions to floatMust terminate at 0.02–0.05C taper current.

Important

The peak voltages differ by only half a volt, so it appears to work. What does the damage is everything after the peak: an equalisation stage that overcharges cells LFP cannot tolerate, and a float stage that never lets go. A pack charged this way for a season will show unexplained capacity loss and, in the worst case, swelling.

In plain English

Practically: when you sell or fit a lithium pack, the old charger must leave with the old battery. Log the charger serial number against the pack. A customer who keeps the lead-acid charger “as a spare” will eventually use it, and the resulting failure will arrive as a warranty claim with no obvious cause.

13.4Fast charging and the trade-off

Higher charge C-rate means more heat, more polarisation, and — near the top of charge and at low temperature — lithium plating. There is no way to fast-charge without paying in one of those currencies.

Technical framing

The compromise used in cars is tapering: high current at low state of charge, reducing progressively as SOC rises, because the plating risk grows as the anode fills. This is why a car charges from 10 to 80 per cent far faster than from 80 to 100.

For a three-wheeler on a depot schedule, fast charging is usually solving a problem you do not have. Slow overnight charging at 0.2C is better for cycle life, cheaper in equipment, lower risk, and it fits the vehicle’s actual idle window. Fast charging earns its cost only where the vehicle’s revenue depends on turning round mid-shift.

13.5Charging practices that extend life

  • Charge to 100 per cent at least weekly so the BMS can balance — but do not leave it sitting there for days. Most passive BMS boards only balance above a threshold around 3.40 V/cell and only while charging, so a fleet that habitually stops at 80 per cent never balances at all. The imbalance accumulates silently for months and then presents as sudden capacity loss. A weekly full charge is a genuine maintenance instruction, not a nicety.
  • Avoid habitually discharging below 10 to 15 per cent. Shallower cycling buys disproportionately more cycles — the DOD relationship is in Chapter 5.
  • Never charge below 0°C. Non-negotiable in a North Indian winter, and it must be enforced by the BMS rather than by instructions to riders. See Chapter 6.
  • Let a hot pack cool before charging. A pack coming off a summer afternoon shift is already above its comfortable range; adding charge heat on top compounds the ageing.
  • Use the matched charger, and record its serial number against the pack. This is how you resolve a warranty dispute in five minutes instead of five weeks.
  • Store at 40 to 60 per cent SOC if the pack will be idle for weeks. Inventory and off-season vehicles both count.

Quick check: test yourself

1.A customer says the new lithium pack “works fine” on their old 60 V lead-acid charger. Is there a problem?

Show answer
Yes, and it will not show for months. The peak voltages are close — about 73.5 V against the 73.0 V LFP needs — which is why it appears to work. The damage comes after the peak: a lead-acid charger runs an equalisation stage that deliberately overcharges, and then floats indefinitely. LFP has no equalisation phase and no tolerance for float, so the pack sits at high SOC accelerating calendar ageing. Take the old charger away with the old battery.

2.A fleet charges to 80 % every night to “be kind to the battery”. Six months later capacity drops sharply. Why?

Show answer
The pack has never balanced. Most passive BMS boards only balance above a threshold around 3.40 V per cell and only while charging, so stopping at 80 % means the balancing circuit has not run once. Small cell-to-cell differences accumulate for months, and eventually one cell hits the cut-off well before the others and the pack’s usable capacity collapses. Schedule a full charge at least weekly — it is maintenance, not a compromise.

3.Why does a charger need to stop rather than float?

Show answer
Because holding a lithium cell at high state of charge is one of the two conditions that accelerate SEI growth, the other being heat. Lead-acid needs float to offset its much higher self-discharge; LFP does not, losing only 2 to 3 per cent a month. A charger that floats is keeping the pack in its worst storage condition continuously, which shows up as calendar ageing the customer will read as premature failure.

4.Is fast charging worth it for a depot-based three-wheeler fleet?

Show answer
Usually not. Fast charging costs cycle life through heat and polarisation, risks plating near the top of charge, and needs more expensive equipment. A depot vehicle has an idle window overnight that comfortably fits a 0.2C charge — around seven hours on a 100 Ah pack at 15 A. Fast charging earns its cost only where revenue depends on turning the vehicle round mid-shift.

Chapter summary

Frequently asked questions

Can I use my old lead-acid charger on a new lithium pack?+

No, and it is the most damaging common error in this market. The peak voltages look close — about 73.5V against the 73.0V a 20S LFP pack needs — which is why it appears to work. The damage comes after the peak: a lead-acid charger runs an equalisation stage that deliberately overcharges, then floats indefinitely. LFP has no equalisation phase and no tolerance for float. The old charger should leave with the old battery.

Why must a lithium charger stop rather than float?+

Because holding a cell at high state of charge is one of the two conditions that accelerate SEI growth, the other being heat. Lead-acid needs float to offset its much higher self-discharge; LFP loses only 2 to 3 per cent a month and does not. A charger that floats keeps the pack in its worst storage condition continuously, producing calendar ageing the customer reads as premature failure.

Should I charge my battery to 100 per cent or stop at 80?+

Charge fully at least weekly, then avoid sitting at 100 per cent for days. Most passive BMS boards only balance above a threshold around 3.40V per cell and only while charging, so a fleet that always stops at 80 per cent never balances at all. Imbalance then accumulates silently for months and presents as sudden capacity loss. A weekly full charge is genuine maintenance, not a compromise.

Is fast charging bad for a battery?+

It costs cycle life through heat and polarisation, and near the top of charge or at low temperature it risks lithium plating. Cars manage this by tapering — high current at low state of charge, reducing as the anode fills, which is why 10 to 80 per cent is far faster than 80 to 100. For a depot-based three-wheeler with an overnight window, 0.2C charging is better in every respect and cheaper in equipment.

What voltage charger does a 20S LFP pack need?+

73.0V — twenty cells at 3.65V each. Not 72V, and not the 73.5V a 60V lead-acid charger delivers. Current rating of 0.2 to 0.5C trades acceptable charge time against long life, which on a 100Ah pack is 20 to 50A. A charger that communicates with the BMS over CAN can additionally be commanded to reduce current, stop, or refuse to start when the pack is cold.

Reviewed by

SG

Sahil Goyal

Co-founder, Wingzman

LinkedIn
SG

Sourabh Goyal

Co-founder, Wingzman

LinkedIn

Battery Fundamentals is an original educational series on lithium battery technology. Threshold tables, cycle-life curves and worked examples use representative values drawn from published product specifications and widely-observed industry patterns, not measured data from a specific product. Always consult the current manufacturer datasheet before making design, purchasing, warranty or certification decisions.